Capillary Zone Electrophoresis CZE

2.1.1. Mechanism

Section 1 of this chapter dealt almost entirely with this form of CE. CZE is characterized by the use of open capillaries and relatively low viscosity buffer systems. Analyte molecules move from one end of the capillary to the other according to the vector sum of electrophoresis and electroosmotic mobility.

2.1.2. Applications

CZE is the most widespread mode of CE. It has been used for analytes as diverse as sodium ions, drugs, and protein molecules. Analyte species can be separated by CZE if they migrate at different velocities in the electrical field.

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