Yym

R4=a-0Me

TABLE 7.1 (CONTINUED) Saikosaponins and Their Structures

Name of Saponin

Structure

Type

91. 11a-Methoxysaikosaponin f III

92. Saikosaponin t III

93. Saikosaponin 15 III

94. Saikosaponin 16 III

95. Rotundioside D III

96. Bupleuroside III III

97. Bupleuroside VI III

98. Bupleuroside IX III

99. Hydroxysaikosaponin a III

100. Hydroxysaikosaponin d III

101. Hydroxysaikosaponin c III

Tetrahydroxyolean-12-en-3ß-yl-[ß-D-glucopyranosyl-(1-2)]-[ß-D-glucopyranosyl-(1-3)]-ß-D-fucopyranoside

103. 16a,23,28-Trihydroxyolean- III

12-en-3ß-yl-[ß-D-glucopyranosyl-(1-2)][ß-D-glucopyranosyl-(1-3)]-ß-D-fucopyranoside

104. Saikosaponin g IV

105. Saikosaponin i IV

106. Prosaikogenin H IV

107. saikosaponin S1: V

108. Rotundioside A V

Structure

R1=ß-OH R2=-H R4=a-OMe R3=ß-D-glu-(1~6)-[a-L-rha-(1~4)-]-ß-D-glu-

R1=ß-OH R2=-H R4=a-OMe R3=ß-D-glu-(1~3)-ß-D-fuc-R1=ß-OH R2=-OH R4=a-OMe R3=ß-D-xyl-(1~2)-ß-D-glu-(1~3)-ß-D-fuc-R1=ß-OH R2=-OH R4=a-OMe R3=ß-D-glu-(1~6)-[a-L-rha-(1~4)-]-ß-D-glu-

R1=a-OH R2=-H R4=a-H R3=a-L-rha-(1~2)-ß-D-glu-(1~2)-ß-D-glu-R1=-OH R2=-OH R4=a-OMe R3=ß-D-glu-(1~3)-ß-D-fuc-(1~) R1=-OH R2=-OH R4=a-OMe C11=O R3=ß-D-glu-(1~3)-ß-D-fuc-R1=-OH R2=-H R4=a-OMe R3=ß-D-glu-(1~3)-ß-D-fuc-R1=ß-OH R2=-OH R4=a-OH R3=ß-D-glu-(1~3)-ß-D-fuc-R1=a-OH R2=-OH R4=a-OH R3=ß-D-glu-(1~3)-ß-D-fuc-R1=ß-OH R2=-OH R4=a-OH R3=ß-D-glu-(1~6)-[a-L-rha-(1~4)-]-ß-D-glu-

R1=ß-OH R2=-OH R4=a-OH R3=ß-D-glu-(1~2)-[ß-D-glu-(1~3)-]-ß-D-fuc-

R1=ß-OH R2=-OH R4=a-OMe R3=ß-D-glu-(1~2)-[ß-D-glu-(1~3)-]-ß-D-fuc-

R1=ß-OH R2=-OH R4=-H R3=ß-D-glu-(1~3)-ß-D-fuc-R1=ß-OH R2=-H R4=-H R3=a-D-glu-(1~6)-[a-L-rha-(1~4)-]- ß-D-glu-

R3=ß-D-fuc-R1=-H R2=ß-D-glu-R3=a-L-arab-(1~3)-ß-D-glu-R1=ß-OH R3=-SO3H R2=ß-D-glu-(1~6)-ß-D-glu-(1~2)-ß-D-glu-(1~6)-ß-D-glu-

Ref.

Ding JK et al., 1986

Liang H et al., 1998a Ding JK et al., 1986 Ding JK et al., 1986

Matsuda H et al.,

1997 Matsuda H et al.,

1997 Matsuda H et al., 1997

Ebata N et al., 1996 Ebata N et al., 1996 Ebata N et al., 1996

Pistelli L et al., 1993a

Pistelli L et al., 1993a

Shimizu K et al.,

1985 Shimizu K et al., 1985

Shimizu K et al.,

1985 Seto et al., 1986d

TABLE 7.1 (CONTINUED) Saikosaponins and Their Structures

Name of Saponin

109. Rotundioside B

110. Rotundioside C

111. Sandrosaponin IX

112. Sandrosaponin X

113. Bupleuroside XII

Structure Type

Traditional Chinese Medicine

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